精品国产中文字幕_国产精品中文久久久久久久_国产精品久久久久久久免费大片_欧美激情第6页_国产精品久久久久久一区二区_99精品在线直播_欧美日韩在线不卡一区_欧美国产日本高清在线_国外成人在线播放_7777kkkk成人观看

只用于動物實驗研究等

General Information

Chemical structure of ITIC; CAS No. 1664293-06-4; Chemical formula: C₉₄H₈₂N₄O₂S₄.

Applications

ITIC represents the start of a new generation of electron-accepting small molecules for organic photovoltaic (OPV) applications. The energy levels of ITIC allow for good alignment with low band-gap polymers, resulting in enhanced charge separation efficiency and reduced energy loss. ITIC also has strong and broad absorption characteristics, from visible to near infrared and peaking at 700 nm, giving it the potential to increase the total absorption of an OPV device.

These properties have enabled ITIC to be the first small molecule to outperform fullerenes as the electron acceptor in an OPV device. When used in conjunction with PBDB-T (PCE12), a power conversion efficiency (PCE) of over 11% was achieved, compared to less than 8% when PC₇₀BM was used as the electron acceptor. Additionally, ITIC proved to have excellent thermal stability, with devices showing no losses after being held at 100 °C for 250 hours [1].

Characterisation (¹H NMR)

¹H NMR spectrum of ITIC in CDCl₃

Literature and Reviews

1. Non-Fullerene Polymer Solar Cells Based on Alkylthio and Fluorine Substituted 2D-Conjugated Polymers Reach 9.5% Efficiency, H. Bin et al., J. Am. Chem. Soc.,138 (2016), 4657−4664; DOI: 10.1021/jacs.6b01744.
2. Fullerene-Free Polymer Solar Cells with over 11% Ef?ciency and Excellent Thermal Stability, W. Zhao et al., Adv. Mater., 28, 4734–4739 (2016); DOI: 10.1002/adma.201600281.
3. An Electron Acceptor Challenging Fullerenes for Ef?cient Polymer Solar Cells, Y. Lin et al., Adv. Mater., 27, 1170–1174 (2015); DOI: 10.1002/adma.201404317.
4. High-Efficiency Nonfullerene Polymer Solar Cells with Medium Bandgap Polymer Donor and Narrow Bandgap Organic Semiconductor Acceptor, L. Gao et al., Adv. Mater., 28, 8288–8295 (2016); DOI: 10.1002/adma.201601595.